Arif Javanshir Efendi

Doctor of Chemical Sciences, Senior Scientific Researcher

19

Investigation of kinetics and mechanism of catalytic oxidation reaction of hydrocarbons and their halogen derivatives. 

The scientific principles of catalytic oxidation of halogen derivatives of aliphatic, olefine, cyclic, dien and aromatic series of hydrocarbons over the surface of vanadium, molybden, phosphor, antimony, cobalt, bismuth oxide catalysts supported on the different carriers with obtaining the important organic compounds: aldehydes, anhydrides and acids, as well of oxydizing dehydration of low molecular alcohols on the alloys of zirconium, vanadium, molybdenum, iron, and their hydrides have been developed. For these processes the active and selective catalytic systems have been synthesized; the rows of their activity and selectivity have been established. The kinetic regularities and mechanisms have been determined for every process. The dynamics of deactivation and reactivation has been studied, the kinetic models have been made up, the new non-traditional ways of their activation were proposed. Taking into account the importance of these processes in solution of ecological problems the principle technological schemes, mathematical models have been elaborated; their optimum projecting is proposed.