StructureInstitutes and
OrganizationsInstitute of Chemical Problems
named after acad. M.F.NagiyevLaboratory № 12
"Modelling of monooxygenaze reactions"
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Phone: | (994 12) 5394691 |
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Head of structural unit: |
Doctor of Chemical Sciences, Professor, Academician |
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Total number of employees: | 12 |
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Main area of activity of the structural unit: |
The development of fundamental bases of biomymetic catalysis in reactions of selective monooxidation-hydroxylation, epoxidation and oxidative dehydrogenation- with hydrogen peroxide. |
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Main scientific achievements of the structural unit: |
The macrokinetic theory of coherently synchronized chemical reactions has been created: definition of the phenomenon of chemical interference and the determinant equation are given. The highly efficient catalytic biomimetators of hydroxylation and epoxidation resisting the action of oxidizer and high temperatures have been developed. The new HO.2 -dependent elementary reactions of oxidation with corresponding kinetic parameters are offered. The new free radical reactions are revealed and thoroughly stu-died: oxidizing fixation of nitrogen, conjugate dehydration, epoxidation and oxidation of alkanes and alkenes in which capacity of hydrogen peroxide to induce the chemical reaction is realized. The conception of chemical conjugation of mitochondrial energetic processes has been worked out and mechanism of action of catalase enzyme has been suggested. The scientific principles of designing of biomimetical sensors-the high sensitive analytical systems are successfully developed. |
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