Gulmamed Ziaddin Suleymanov
Doctor of Chemical Sciences, professor

11

Synthesis, study of coordination compounds with organic and metal carbonyl ligands of the transitional and rare earth elements and preparation of the new catalytic systems on their base.

The modifiers of the new class of coordinaton and metal organic compounds of some transition and rare earth elements with organic and metal carbonyl ligands were synthesized. By the study of ratio between structure and the properties of these compounds the influence of metal atom and a nature of the ligands bound with it on first, reactivity, and, second, catalytic and antidetonation properties were determined, and developed the new scientific direction. Some of these compounds were used as octane improving composition additives for motor and diesel fuels substituting tetraethyl lead. The documents of the project were prepared for introducing one of them - ferrocene containing composition "Cryscat", made on the base of chemical and oil chemical raw of the republic. Some of metal carbonyl compounds were used for catalytic treatment  of sulfurated oil products with reduction to elementary sulfur at 200-600C. The catalytic systems were made for Z-forming process on base of Zn-Mo.