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Main area of activity of the structural
unit: |
Development of
physical-chemical bases of creation of active composite , including hybrid
and nanocomposits;
Study of mechanisms of the
electret, piro-, piezo-, photoelectric, photovoltaic, electro- and thermo
luminescent, piezoresistive, varistor, posistor effects in composites on
the basis of various polymers, ferroelectrics and semiconductors;
Development of physical base
of creation of multifunction converters on the bases of above named
composites;
Research of physics of
discharge plasma between dielectrics and use of the gas category in the
technological purposes;
Influence of plasma of the
gas category on physical-mathematical and electric properties of polymer
dielectrics under various conditions, including cryogenic temperatures.
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Main scientific achievements of the
structural unit: |
A complex research of mathematical, electro-thermo luminescent, thermal
properties, boundary polarization, electron-ion and relaxation processes,
interface phenomena and a charge state of composites in carried out in the
laboratory. A possible mechanism of formation of the piro-, piezoelectric,
electret. posistor, varistor, piezoresistive, photoelectric, photovoltaic
effects in disorder systems of -piezoelectric and polymer-semiconductor is
offered.
By research of pyroelectric properties of composites on the bases of
polymer-piezoceramics it is established that the reason of formation of the
pyroelectric effect is high
reorientation polarization in a piezo-phase under action of an electric
field of the injected charges on the phase boundary. It is found that
piezoceramics having a domain-orientation polarization which is distinct
from 180° and a rhombo hedral structure are effective
components for pyroelectric composites.
By research of electret properties of composites it is established that the
reason of occurrence of the electret effect in composites
structure of a polymer and formation of a quasineutral
system of type the injected electron and oriented on a direction of a field
the domain in a particle as a result of polarization. The mechanism
of change of an efficient electret charge and electret of a potential
difference from temperature and an electric intensity in the polymer-
piezoelectric composites is offered. It is found that for electret
properties composites obtained on the base of the rhombo hedral
piezoceramics are effective than composites on the base of the tetragonal
piezoceramics. The model of electret composites and on the base of this
model the mechanism of occurrence of electret properties in no polar
polymers after dispersion their by piezoelectric particles are offered.
Researches showed that a dispersion of no polar (polyolefin) and polar
(fluor carbon) polymers by semiconductor and piezoelectric particles leads
to formation in the composites on the basis of their of the varistor and
posistor effects due to formation of a potential barrier on the phase
boundary and the change of its under action of temperature and an electric
field.
It is established that a structure (a polarity, super molecular structure),
a dielectric constant and an increase of a volume at the melting point of a
polymer matrix substantially influence on the varistor and posistor
properties of polymer-semiconductor composites due to an immediate
dependence on their the value of potential barrier on the
polymer-semiconductor phase boundary.
The technology and methods of obtaining of high effective composition
posistor and resistor materials in the polymer-semiconductor system are
developed.
On the composition polymer elements are developed electro acoustic
converters, hydro acoustic send-receive aerials, devices of acoustic
electronics, opto-acoustic transducers, gauges of tones of Korotkov,
vibration pick-ups, seysmo-pick-ups, gauges of static and dynamic pressures,
many of which have found serial application at factories and the enterprises
of the various Ministries.
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