The efficient methods of synthesis of high unsaturated functional compounds of vinylacetylene, allylacetylene, allene, 1,3- and 1,4-enyne series have been developed. The regularities of reaction of diene condensation with participation of cyclic dienes and inactivated dienophiles have been studied and the mechanism of reaction has been proposed. The action of dihaloidcarbenes, generated in conditions of interphase catalysis with compounds of 1,3- and 1,4-enyne series has been comparatively studied and the regularities of reaction have been established. The methods of synthesis of silicon-, boron-, phosphor- and halogen containing compounds in the presence of metal complex catalysts have been developed. The synthesized compounds possessing high biological activity can be used as efficient plasticizers, modifiers, inhibitors,etc.

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